当前位置: X-MOL 学术ACS Catal. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Phosphoranyl Radical Fragmentation Reactions Driven by Photoredox Catalysis.
ACS Catalysis ( IF 11.3 ) Pub Date : 2020-06-05 , DOI: 10.1021/acscatal.0c01923
James A Rossi-Ashton 1 , Aimee K Clarke 1 , William P Unsworth 1 , Richard J K Taylor 1
Affiliation  

Photocatalytic generation of phosphoranyl radicals is fast emerging as an essential method for the generation of diverse and valuable radicals, typically via deoxygenation or desulfurization processes. This Perspective is a comprehensive evaluation of all studies using phosphoranyl radicals as tunable mediators in photoredox catalysis, highlighting how two distinct methods for phosphoranyl radical formation (radical addition and nucleophilic addition) can be used to generate versatile radical intermediates with diverse reactivity profiles.

中文翻译:


光氧化还原催化驱动的磷酰自由基断裂反应。



光催化生成正膦基自由基正在迅速成为生成各种有价值的自由基的重要方法,通常通过脱氧或脱硫过程。本视角是对所有使用正膦基自由基作为光氧化还原催化中的可调介体的研究的综合评估,强调了如何使用两种不同的正膦基自由基形成方法(自由基加成和亲核加成)来生成具有不同反应性的多功能自由基中间体。
更新日期:2020-07-02
down
wechat
bug