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Low-Temperature Heat Capacity of M -Type Terbium Orthotantalate and Schottky Anomaly
Russian Journal of Inorganic Chemistry ( IF 1.8 ) Pub Date : 2020-06-05 , DOI: 10.1134/s0036023620050083
K. S. Gavrichev , A. V. Tyurin , V. N. Gus’kov , P. G. Gagarin , A. V. Gus’kov , M. A. Ryumin

Abstract

The molar heat capacity of М-type terbium orthotantalate was measured by adiabatic calorimetry in the range 18–346 K. Smoothed heat capacity values were used to calculate the entropy, enthalpy gain, and reduced Gibbs free energy. The Schottky anomalous heat capacity in lanthanide compounds and its evaluation methods were analyzed.


中文翻译:

M型原钽酸b的低温热容与肖特基异常

摘要

通过绝热量热法测量了М型原钽酸ate的摩尔热容。该热容值用于计算熵,焓增和降低的吉布斯自由能。分析了镧系元素化合物的肖特基异常热容及其评估方法。
更新日期:2020-06-05
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