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Recent Advances in Nanocasting Cobalt-Based Mesoporous Materials for Energy Storage and Conversion
Electrocatalysis ( IF 2.7 ) Pub Date : 2020-06-05 , DOI: 10.1007/s12678-020-00608-9
Ali Saad , Zhixing Cheng , Hangjia Shen , Tiju Thomas , Minghui Yang

The generation of novel mesoporous materials with well-defined structure and accessible pore networks is helpful in both fundamental and energy-related research. Nanocasting mesoporous earth-abundant materials and their composite materials offer opportunities to make electrochemically active materials that allow scalable production and cost-effectiveness. Recently, due to their intrinsic open pore structure as well as high surface areas, various mesoporous cobalt-based ordered materials have been applied to electrocatalysis, rechargeable batteries, and supercapacitors. In this review, we have critically evaluated the advancements made specifically in three- and two-dimensionally (3D/2D) electrode Co-based materials (oxides, nitrides, phosphides, and sulfides). We outline foreseeable challenges and issues for the utilization of mesostructured cobalt-based electrode materials. This review also provides guidelines for further work to those who work on energy-related applications of mesoporous cobalt-based materials.

Nanocast cobalt-based mesoporous materials hold great promise in the application of energy conversion and storage. Herein, recent advances of two-dimensional and three-dimensional mesoporous cobalt-based mesoporous oxides, nitrides, phosphides, and sulfides used for electrocatalysis, rechargeable batteries, and supercapacitors were discussed. Moreover, the structure-property relationships of these materials and current challenges in both nanoarchitecture design and their applications in electrochemical energy devices are proposed. An outlook is provided for future research.



中文翻译:

纳米铸造钴基介孔材料用于储能和转化的最新进展

具有确定的结构和可及的孔网络的新型介孔材料的产生,对基础研究和与能源有关的研究都有帮助。纳米浇铸介孔富地球材料及其复合材料为制造电化学活性材料提供了机会,该材料可实现可扩展的生产和成本效益。近年来,由于其固有的开孔结构以及高表面积,各种中孔钴基有序材料已被应用于电催化,可充电电池和超级电容器。在这篇综述中,我们严格评估了在3维和二维(3D / 2D)电极Co基材料(氧化物,氮化物,磷化物和硫化物)中所取得的进步。我们概述了介孔结构钴基电极材料的利用可预见的挑战和问题。这篇综述还为从事介孔钴基材料的能源相关应用的人员提供了进一步工作的指南。

纳米铸造的钴基介孔材料在能量转换和存储的应用中具有广阔的前景。在此,讨论了用于电催化,可充电电池和超级电容器的二维和三维介孔钴基介孔氧化物,氮化物,磷化物和硫化物的最新进展。此外,提出了这些材料的结构特性关系以及当前在纳米体系结构设计中的挑战及其在电化学能量装置中的应用。为将来的研究提供了前景。

更新日期:2020-06-05
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