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A Star‐Shaped Triazine‐Based Vitamin B5 Copper(II) Nanocatalyst for Tandem Aerobic Synthesis of Bis(indolyl)methanes
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-06-04 , DOI: 10.1002/ejoc.202000270
Benyamin Hasanpour 1 , Maasoumeh Jafarpour 1 , Ameneh Eskandari 1 , Abdolreza Rezaeifard 1
Affiliation  

Anchoring a bio‐relevant Cu(II) vitamin B5 complex to a triazine ring results in a reusable star‐shaped catalyst for the TEMPO‐mediated aerobic oxidation of benzylic alcohols followed by coupling with indole derivatives producing bis(indolyl)methanes in desired yields and excellent selectivity.
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中文翻译:

一种星形三嗪类维生素B5铜(II)纳米纳米催化剂,用于串联好氧合成双(吲哚基)甲烷。

将具有生物相关性的Cu(II)维生素B5复合物锚固到三嗪环上,可得到可重复使用的星形催化剂,用于TEMPO介导的苄醇的好氧氧化,然后与吲哚衍生物偶联,以所需的收率生产双(吲哚基)甲烷。极好的选择性。
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更新日期:2020-07-16
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