Chiral Dinuclear Benzyliminobinaphthoxy‐Palladium Catalyst for Asymmetric Mannich Reaction of Aldimines and Isatin‐Derived Ketimines with Alkylmalononitriles,Advanced Synthesis & Catalysis

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Chiral Dinuclear Benzyliminobinaphthoxy‐Palladium Catalyst for Asymmetric Mannich Reaction of Aldimines and Isatin‐Derived Ketimines with Alkylmalononitriles
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2020-06-02 , DOI: 10.1002/adsc.202000447
Ayu Nakamura ₁ , Satoru Kuwano ₁ , Junchuan Sun _{1,

2} , Kensuke Araseki ₁ , Eri Ogino ₁ , Takayoshi Arai ₁

Affiliation

A newly developed dinuclear bis(benzylimino)binaphthol (BIB )−Pd complex showed good catalytic activity for the Mannich reaction of aldimines and isatin‐derived ketimines with alkylmalononitriles to give the products in a highly enantioselective manner.

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