Base promoted regioselective aromatization for the preparation of substituted 3‐hydroxybenzene dicarboxylate,Journal of Heterocyclic Chemistry

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Base promoted regioselective aromatization for the preparation of substituted 3‐hydroxybenzene dicarboxylate
Journal of Heterocyclic Chemistry ( IF 2.0 ) Pub Date : 2020-06-03 , DOI: 10.1002/jhet.4024
Weihang Guo ₁ , Xianheng Wang ₁ , Changkuo Zhao ₁ , Yuhe Wang ₂

Affiliation

A new convenient base promoted aromatization process has been developed to prepare substituted 3‐hydroxybenzene dicarboxylate using commercially available materials. In particular, regioselectivity will occur for substrates with mono‐substitution at 5‐ or 6‐position. This new process provides less reaction steps and moderate yields, and can be used extensively in the synthesis of other substrates to functionalize phenol esters.

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