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Design of Bowl-Shaped N-Hydroxyimide Derivatives as New Organoradical Catalysts for Site-Selective C(sp3 )-H Bond Functionalization Reactions.
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2020-06-02 , DOI: 10.1002/anie.202003982
Terumasa Kato 1 , Keiji Maruoka 1, 2, 3
Affiliation  

A series of new bowl‐shaped N‐hydroxyimide derivatives has been designed and used as selective organoradical catalysts. A number of these bowl‐shaped N‐hydroxyimide derivatives exhibit excellent site‐selectivity in the amination of benzylic C(sp3)−H bonds in aromatic hydrocarbon substrates.

中文翻译:

碗形N-羟基酰亚胺衍生物的设计作为位点选择性C(sp3)-H键官能化反应的新有机催化剂。

已经设计了一系列新的碗形N-羟基酰亚胺衍生物,并将其用作选择性有机自由基催化剂。这些碗形N酰亚胺衍生物中的许多在芳烃底物中的苄基C(sp 3)-H键的胺化反应中表现出出色的位点选择性。
更新日期:2020-08-10
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