A study by our laboratory shows that air, light and moisture stable O-(tert-butyl) Se-phenyl selenocarbonate could be employed as a safer, practical and efficient alternative to generate “in situ” benzeneselenol or benzeneselenolate anion under different and transition metal-free conditions. This procedure seems to be of general application since the nucleophilic selenium species obtained can be trapped by electrophiles such as alkyl halides, epoxides and electron-deficient alkenes and alkynes under different reaction conditions.

中文翻译：

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O-（叔丁基）硒代硒代碳酸硒酯：苯硒酚的便捷，稳定，无金属的前体

我们实验室的研究表明，空气，光和湿气稳定的O-（叔丁基）硒代硒代硒代碳酸酯可以用作更安全，实用和高效的替代品，以在不同的过渡金属下生成“原位”苯硒醇或苯硒酸根阴离子。无条件。该方法似乎是通用的，因为在不同的反应条件下，所得到的亲核硒物质可能会被亲电试剂（例如卤代烷，环氧化物和缺电子的烯烃和炔烃）捕获。