Buchwald‐Type Ligands on Gold(I) Catalysis,Israel Journal of Chemistry

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Buchwald‐Type Ligands on Gold(I) Catalysis
Israel Journal of Chemistry ( IF 2.3 ) Pub Date : 2020-02-24 , DOI: 10.1002/ijch.201900179
Giuseppe Zuccarello _{1,

2} , Margherita Zanini _{1,

2} , Antonio M. Echavarren _{1,

2}

Affiliation

Dialkyl biarylphosphine ligands, presented in the context of Pd‐catalyzed cross‐coupling reactions, have been extensively applied in gold(I) catalysis giving rise to numerous transformations and reaction pathways otherwise inaccessible under the action of other gold(I) catalysts. This review emphasizes how this privileged ligand class, as well as recent modifications on the biarylphosphine motive, have triggered the discovery of new reactivities in our research program. Finally, the introduction of chiral information on the ligand scaffold provides new solutions to challenging gold(I)‐catalyzed enantioselective transformations.

中文翻译：

金（I）催化的布赫瓦尔德型配体

在Pd催化的交叉偶联反应中提出的二烷基联芳基膦配体已被广泛应用于金（I）催化中，从而导致许多转化和反应途径，而在其他金（I）催化剂的作用下则是无法达到的。这篇综述强调了这种优先的配体类别以及对联芳基膦动机的最新修饰如何触发了我们研究计划中新反应性的发现。最后，在配体支架上引入手性信息为挑战金（I）催化的对映选择性转化提供了新的解决方案。

更新日期：2020-02-24

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