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Development of Multi-Catalytic Strategies Based on the Combination between Iron-/Copper- and Organo-Catalysis
Israel Journal of Chemistry ( IF 2.3 ) Pub Date : 2020-04-28 , DOI: 10.1002/ijch.202000018
Adrien Quintard 1
Affiliation  

Despite the latest advances in catalysts efficiency, using one single catalytic activation mode can lead to considerable limitations. To overcome reactivity or selectivity issues, multi-catalytic combinations can represent interesting alternatives. This manuscript reviews the recent transformations developed in my group through the combination between cheap iron or copper complexes and organo-catalysis. Combining these activation modes enables considerable synthetic economies inconceivable by using one single catalyst. The strategies developed to combine efficiently different catalysts as well as the resulting synthetic applications are discussed.

中文翻译:

基于铁/铜和有机催化结合的多催化策略的发展

尽管在催化剂效率方面取得了最新进展,但使用一种单一的催化活化模式会导致相当大的局限性。为了克服反应性或选择性问题,多催化组合可以代表有趣的替代品。这份手稿回顾了我的小组最近通过廉价的铁或铜配合物与有机催化的结合而发展起来的转化。将这些活化模式结合起来,可以通过使用一种单一的催化剂实现不可想象的相当大的合成经济性。讨论了有效结合不同催化剂的策略以及由此产生的合成应用。
更新日期:2020-04-28
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