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Impact of volatile organic compounds and photochemical activities on particulate matters during a high ozone episode at urban, suburb and regional background stations in Beijing
Atmospheric Environment ( IF 5 ) Pub Date : 2020-09-01 , DOI: 10.1016/j.atmosenv.2020.117629 Ping Shao , Xiaobin Xu , Xiaoling Zhang , Jing Xu , Ying Wang , Zhiqiang Ma
Atmospheric Environment ( IF 5 ) Pub Date : 2020-09-01 , DOI: 10.1016/j.atmosenv.2020.117629 Ping Shao , Xiaobin Xu , Xiaoling Zhang , Jing Xu , Ying Wang , Zhiqiang Ma
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Abstract Volatile organic compounds (VOCs) play key roles in the formation of particulate matter (PM) and oxidants and hence enhance the summertime air pollution. With data analysis from various field observations (urban station: Haidian, HD; suburb station: Changping, CP; regional background station: Shangdianzi, SDZ) in June 2011, we found that the mean O3 concentrations throughout the observation period can be arranged in order: SDZ＞CP＞HD. The mean PM concentrations can be arranged in order: HD＞CP＞SDZ. The mean concentration of total VOCs at HD was close to that at CP, but much higher than that at SDZ. Oxygenated volatile organic compounds (OVOCs) made the largest portion of VOCs (~40%) at the three stations, followed by alkanes and alkenes. Good positive correlations between the concentrations of PM and Ox (=O3＋NO2) at high air temperature (≥30 °C at HD and CP; ≥28 °C at SDZ) and low RH (≤60%) were found in the daytime (07:00–18:00 LT). However, the PM concentrations were partly negatively correlated with Ox at lower temperatures (≤26 °C at HD and CP; ≤22 °C at SDZ) and higher RH (≥80%). The PM concentrations were found either positively (HD and CP) or negatively (SDZ) correlated with aromatics at high temperature and low RH. The aging degree of air masses at the three stations can be arranged in order: SDZ＞CP＞HD. This can qualitatively explain the different PM−aromatics correlations. Our data suggested the other groups of VOCs may promote the increase of PM concentrations unless the PM levels become higher than 140 μg m−3 under humid conditions. This study confirms the importance of VOCs in the formation of summertime PM and oxidants over Beijing.
更新日期：2020-09-01
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