Abstract

The reactions of oligomeric aluminoborophosphates with hexamethylenediamine and pentylamine are studied, as are the properties of the obtained products which are polycomplexes with the participation of hydrogen bonds, which is confirmed by the results of quantum chemical calculations. The changes in the relaxation properties of the polycomplexes are determined by the softening and flow temperatures measured by thermomechanical analysis. It is shown that the modification of polyphosphates by primary amines under mild conditions leads to an increase in the water resistance of the obtained polycomplexes.

中文翻译：

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金属磷酸盐和伯胺的热塑性聚合物

摘要

研究了低聚铝硼磷酸盐与六亚甲基二胺和戊胺的反应，以及获得的产物的性质，该产物是具有氢键参与的多配合物，这由量子化学计算的结果证实。聚复合物的弛豫特性的变化取决于通过热力学分析测得的软化温度和流动温度。结果表明，伯胺在温和条件下对多磷酸盐的改性导致所得到的多配合物的耐水性提高。