Abstract—

The influence of catalytic additives (various organometallic and inorganometallic compounds) in chlorinated polyvinyl chloride on the formation of carbon nanofibers on its surface under a high-power ion beam of nanosecond duration is studied. Ferrocene, which provides the growth of long (up to 10 μm) nanofibers with a narrow diameter distribution and a small number of pores in the underlying polymer layer, seems to be the optimal catalyst for chlorinated polyvinyl chloride. We found that carbon nanofibers grow on the surface of chlorinated polyvinyl chloride containing zinc chloride as a catalytic additive. This fact indicates that there is a new mechanism for the growth of carbon nanofibers on the surface of chloropolymers under high-power radiation conditions.

中文翻译：

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高功率离子束下催化添加剂对氯化聚氯乙烯表面纳米结构碳层形成的影响

摘要—

研究了氯化纳聚氯乙烯中催化添加剂（各种有机金属和无机金属化合物）对其在纳秒级高功率离子束作用下表面碳纳米纤维形成的影响。二茂铁可以提供长（最多10μm）纳米纤维的生长，其直径分布窄且下面的聚合物层中有少量孔，似乎是氯化聚氯乙烯的最佳催化剂。我们发现碳纳米纤维在含有氯化锌作为催化添加剂的氯化聚氯乙烯表面上生长。这一事实表明，在高功率辐射条件下，存在一种新的机制来使碳纳米纤维在含氯聚合物表面上生长。