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The Synthesis of (2 S , 3 S , 4 R )-2,3-Dialkyl- N -Phenyl-1,2,3,4-Tetrahydro-4-Quinolinamines in the Presence of Crystalline and Amorphous Aluminosilicates
Petroleum Chemistry ( IF 1.3 ) Pub Date : 2020-05-06 , DOI: 10.1134/s0965544120040088
N. G. Grigor’eva , S. A. Kostyleva , A. S. Artem’eva , S. V. Bubennov , B. I. Kutepov

Abstract

The catalytic activity of micro- and micro–meso–macroporous zeolites of the FAU structural type and an ASM mesoporous aluminosilicate in the reaction of aniline with C3–C5 aldehydes has been studied. It has been established that under the studied conditions, (2S, 3S, 4R)-2,3-dialkyl-N-phenyl-1,2,3,4-tetrahydro-4-quinolinamines are the main products formed over the tested catalysts with the selectivity of up to 71%.


中文翻译:

晶体和无定形硅铝酸盐存在下(2 S,3 S,4 R)-2,3-二烷基-N-苯基-1,2,3,4-四氢-4-喹啉胺的合成

摘要

研究了FAU结构类型的微和微介孔大分子沸石和ASM中孔铝硅酸盐在苯胺与C 3 -C 5醛反应中的催化活性。已经确定,在研究的条件下,(2 S,3 S,4 R)-2,3-二烷基-N-苯基-1,2,3,4-四氢-4-喹啉胺是在被测试的催化剂具有高达71%的选择性。
更新日期:2020-05-06
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