Abstract

The peroxide oxidation of thiophene, thioanisole, and dibenzothiophene in the presence of Ce, Zr, Ce + Zr, W, and W + Zn oxide layers formed by plasma electrolytic oxidation on the titanium surface was studied. The composition of the resulting composites was found to affect the activity and conversion of the organosulfur substrates. It was shown by the radical inhibition method that the composites differed in the mechanism of their catalytic action.

中文翻译：

---

等离子体电解氧化形成的氧化物层组成对过氧化物氧化脱硫机理的影响

摘要

研究了在钛表面上通过等离子电解氧化形成的Ce，Zr，Ce + Zr，W和W + W Zn氧化物层的存在下噻吩，硫代苯甲醚和二苯并噻吩的过氧化物氧化。发现所得复合材料的组成影响有机硫底物的活性和转化率。自由基抑制法表明，复合材料的催化作用机理不同。