Abstract The monomer 1H,1H-perfluoro-4-methyl-3,6-dioxaoctyl methacrylate (PFMOM) has been synthesized for the first time. PFMOM–vinyl pivalate (VP) copolymers and PFMOM–VP–hydroxyethyl methacrylate (HEMA) terpolymers have been synthesized by radical polymerization in supercritical carbon dioxide, and the phase behavior of the resulting polymers in CO 2 has been studied. The morphology and hydrophobic properties of copolymer coatings applied to textile substrates from solutions in supercritical CO 2 have been examined.

中文翻译：

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在超临界二氧化碳中制备的聚（新戊酸乙烯酯-co-1H,1H-perfluoro-4-methyl-3,6-dioxaoctyl methacrylate）的疏水性能

摘要 首次合成了单体1H,1H-全氟-4-甲基-3,6-二氧辛基甲基丙烯酸酯(PFMOM)。PFMOM-新戊酸乙烯酯 (VP) 共聚物和 PFMOM-VP-甲基丙烯酸羟乙酯 (HEMA) 三元共聚物通过自由基聚合在超临界二氧化碳中合成，并研究了所得聚合物在 CO 2 中的相行为。已经研究了从超临界 CO 2 溶液中施加到纺织品基材上的共聚物涂层的形态和疏水性能。