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Effects of magnesium loading on ammonia capacity and thermal stability of activated carbons
Korean Journal of Chemical Engineering ( IF 2.9 ) Pub Date : 2020-06-01 , DOI: 10.1007/s11814-020-0508-3
Ji Hye Park , Haroon Ur Rasheed , Kwang Hee Cho , Hyung Chul Yoon , Kwang Bok Yi

Mg-loaded activated carbons were prepared by adding various amounts of Mg (1 to 20 wt%) via ultrasonic-assisted impregnation to investigate the effects on the adsorption and desorption characteristics of ammonia. Mg-loaded activated carbons were characterized by TGA, BET, SEM, EDS mapping, and NH 3 -TPD analysis. Mg was homogeneously dispersed on the activated carbon and NH 3 -TPD analysis confirmed improved desorption and thermal stability for the 10 wt% Mg sample, named AC-Mg(10). AC-Mg(10) retained the highest desorption for five cycles and showed average desorption amount of 0.788 mmol NH 3 /g. During the breakthrough analysis, the AC-Mg(10) showed an initial ammonia adsorption capacity of 0.81 mmol NH 3 /g and average adsorption capacity of 0.69 mmol NH 3 /g over 30 adsorption and desorption cycles.

中文翻译:

镁负载量对活性炭氨容量和热稳定性的影响

通过超声辅助浸渍添加不同量的镁(1 至 20 wt%)来制备负载镁的活性炭,以研究对氨吸附和解吸特性的影响。通过 TGA、BET、SEM、EDS 映射和 NH 3 -TPD 分析表征了负载镁的活性炭。Mg 均匀分散在活性炭上,NH 3 -TPD 分析证实了 10 wt% Mg 样品(命名为 AC-Mg(10))的解吸和热稳定性得到改善。AC-Mg(10) 在五个循环中保持最高的解吸量,平均解吸量为 0.788 mmol NH 3 /g。在突破分析过程中,AC-Mg(10) 在 30 次吸附和解吸循环中显示出初始氨吸附容量为 0.81 mmol NH 3 /g,平均吸附容量为 0.69 mmol NH 3 /g。
更新日期:2020-06-01
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