Abstract A series of phthalocyanine-containing liquid-crystalline compounds (LCCs) are prepared by use of polystyrene sulfonic acid, copper phthalocyanine and an isonicotinate compound via self-assembly. The liquid crystal behavior of LCCs is identified using a polarizing microscope, differential scanning calorimetry, and X-ray diffraction measurements. The LCCs exhibit a helical columnar phase structure, and the liquid crystal behavior of the LCCs is adjusted by changing the composition of the compounds. A series of oriented LCC films are fabricated under different applied electric field intensity at liquid-crystalline temperature. The ionic conductivity is investigated by use of a Li solution passing through the orientated LCC films. Compared with the non-orientated samples, the samples orientated by 25 V/m of electric field show nearly 2-fold increase of conductivity, which is up to 4.0 × 10−4 S cm−1.

中文翻译：

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含酞菁液晶化合物薄膜的自组装和离子电导率

摘要 以聚苯乙烯磺酸、酞菁铜和异烟酸酯类化合物为原料，通过自组装制备了一系列含酞菁的液晶化合物（LCCs）。使用偏光显微镜、差示扫描量热法和 X 射线衍射测量确定 LCC 的液晶行为。LCCs表现出螺旋柱状相结构，LCCs的液晶行为是通过改变化合物的组成来调节的。在液晶温度和不同的外加电场强度下制备了一系列取向的LCC薄膜。通过使用通过定向 LCC 薄膜的锂溶液来研究离子电导率。与非定向样品相比，