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Effect of cysteine using Fenton processes on decolorizing different dyes: a kinetic study
Environmental Technology ( IF 2.8 ) Pub Date : 2020-05-29
Márcio Daniel Nicodemos Ramos, Larissa Aquino Sousa, André Aguiar

Amino acid cysteine has been used as reducing mediator with the aim of improving dye degradation by homogeneous Fenton processes (Fe2+/H2O2 and Fe3+/H2O2). Through its known Fe3+-reducing activity, this amino acid can enhance the production of reactive oxygen species as HO (hydroxyl radical) and its pro-oxidant properties have been verified while decolorizing diverse dyes in the present work. Its presence enhanced decolorization of Methyl Orange, Phenol Red, Safranin T, Rhodamine B, Reactive Black 5 and Reactive Yellow 2, mainly in reactions initially containing Fe3+ as a catalyst (Fe3+-reactions). E.g. Fe3+/H2O2 and Fe3+/H2O2/cysteine systems decolorized 27% and 44% of Phenol Red after 60 min, respectively. A kinetic modeling analysis has revealed that 1st-order and mainly 2nd-order kinetic models were well fitted to both Fe2+- and Fe3+-reactions data. Improvements in reaction rate constants have been observed by adding cysteine. In experiments performed at varied temperatures, it was found a decrease in activation energy (Ea) due to cysteine addition while decolorizing Safranin T: Ea decreased from 104.6 to 88.9 kJ mol-1 for Fe3+-reactions and from 81.0 to 52.2 kJ mol-1 for Fe2+-reactions. Therefore, it was found that cysteine decreases the energy barrier so as to improve Fenton-based decolorization reactions.



中文翻译:

使用Fenton工艺的半胱氨酸对不同染料脱色的动力学研究

氨基酸半胱氨酸已被用作还原介体,目的是通过均质的Fenton工艺(Fe 2+ / H 2 O 2和Fe 3+ / H 2 O 2)改善染料降解。通过其已知的还原Fe 3+的活性,该氨基酸可以增强活性氧的生成,如HO (羟基自由基),并且在本研究中使多种染料脱色的同时,还证实了其促氧化剂的特性。它的存在增强了甲基橙,苯酚红,番红花T,若丹明B,活性黑5和活性黄2的脱色,主要是在最初包含Fe 3+作为催化剂(Fe 3+-反应)。例如,Fe 3+ / H 2 O 2和Fe 3+ / H 2 O 2 /半胱氨酸体系在60分钟后分别使27%和44%的酚红脱色。动力学建模分析表明,1阶和主要2个第二阶动力学模型较好地拟合到两个铁2+ -和Fe 3+ -reactions数据。通过添加半胱氨酸已观察到反应速率常数的改善。在不同温度下进行的实验中,发现由于半胱氨酸添加而使藏红素T:Ea脱色时活化能(Ea)降低从104.6降至88.9千焦耳摩尔-1为铁3+ -reactions和从81.0到52.2千焦摩尔-1为铁2+ -reactions。因此,发现半胱氨酸降低了能垒,从而改善了基于Fenton的脱色反应。

更新日期:2020-05-29
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