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Condensation of chloromethanes and their binary systems with triphenylphosphine induced by low‐voltage discharges
Plasma Processes and Polymers ( IF 2.9 ) Pub Date : 2020-05-28 , DOI: 10.1002/ppap.201900247 Ivan V. Bodrikov 1 , Evgeniy Y. Titov 1 , Andrey Y. Subbotin 1 , Iosif I. Grinvald 1 , Dmitry Y. Titov 1 , Evgeny N. Razov 2
Plasma Processes and Polymers ( IF 2.9 ) Pub Date : 2020-05-28 , DOI: 10.1002/ppap.201900247 Ivan V. Bodrikov 1 , Evgeniy Y. Titov 1 , Andrey Y. Subbotin 1 , Iosif I. Grinvald 1 , Dmitry Y. Titov 1 , Evgeny N. Razov 2
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Solid structures of different shapes, hydrogen chloride, and a small number of liquid products are formed from chloromethanes (CH2Cl2 and CHCl3) and binary systems with triphenylphosphine (CH2Cl2 + PPh3, CHCl3 + PPh3, and CCl4 + PPh3) under the action of a liquid‐phase low‐voltage discharge (60‐V DC). It is observed that triphenylphosphine additives sharply increase the reactivity of CCl4. Besides, a quantum chemical simulation of chloromethane transformation mechanism in the binary systems with triphenylphosphine is conducted, together with the likely mechanism of chloromethane conversion into active particles under the action of a liquid‐phase low‐voltage pulsed discharge.
中文翻译：
低压放电引起的三苯基膦与氯甲烷及其二元系统的缩合
由氯甲烷（CH 2 Cl 2和CHCl 3）和三苯膦（CH 2 Cl 2 + PPh 3，CHCl 3 + PPh 3和）形成的二元体系形成不同形状的固体结构，氯化氢和少量液体产物。CCl 4 + PPh 3）在液相低压放电（60V DC）的作用下。观察到三苯基膦添加剂可显着提高CCl 4的反应活性。此外，还进行了三苯基膦二元体系中氯甲烷转化机理的量子化学模拟，以及在液相低压脉冲放电作用下氯甲烷转化为活性颗粒的可能机理。
更新日期：2020-05-28
中文翻译：
低压放电引起的三苯基膦与氯甲烷及其二元系统的缩合
由氯甲烷（CH 2 Cl 2和CHCl 3）和三苯膦（CH 2 Cl 2 + PPh 3，CHCl 3 + PPh 3和）形成的二元体系形成不同形状的固体结构，氯化氢和少量液体产物。CCl 4 + PPh 3）在液相低压放电（60V DC）的作用下。观察到三苯基膦添加剂可显着提高CCl 4的反应活性。此外，还进行了三苯基膦二元体系中氯甲烷转化机理的量子化学模拟，以及在液相低压脉冲放电作用下氯甲烷转化为活性颗粒的可能机理。
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