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Copper-catalyzed N–H insertion reactions from sulfoxonium ylides
Tetrahedron ( IF 2.1 ) Pub Date : 2020-05-29 , DOI: 10.1016/j.tet.2020.131313
Lucas G. Furniel , Antonio C.B. Burtoloso

The first use of copper(II) as an efficient catalyst for N–H insertion reactions between anilines and α-carbonyl sulfoxonium ylides is described. Products, 39 arylglycine derivatives, were obtained in yields up to 97% employing a simple and fast experimental procedure.



中文翻译:

铜催化亚砜基sulf的NH插入反应

描述了铜(II)作为苯胺和α-羰基亚砜基鎓盐之间NH插入反应的有效催化剂的首次用途。通过简单,快速的实验程序,获得了39种芳基甘氨酸衍生物,收率高达97%。

更新日期:2020-05-29
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