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Structural and Photo-luminescence examination of red emissive Eu3+-doped nanophosphor synthesized via solution-combustion method
Chemical Physics Letters ( IF 2.8 ) Pub Date : 2020-05-29 , DOI: 10.1016/j.cplett.2020.137657
Heena Dahiya , Anju Siwach , Manju Dahiya , Amanvir Singh , Sonia Nain , Mandeep Dalal , S.P. Khatkar , V.B. Taxak , Dinesh Kumar

Eu3+-doped Ba3YP3O12 nanoparticles were prepared by the solution-combustion method. Rietveld refinement confirmed that the system crystallizes in cubic structure with I-43d (2 2 0) space group. Spherical shaped particles in nano range were observed which are responsible for improved luminescence. The 4.9 eV optical band-gap of the host shows that it as a good aspirant for lanthanide activators. The Photoluminescence emission spectrum demonstrates prevailing emission peak assigning to 5D07F2 transition at 612 nm of Eu3+ ions when energized at a wavelength of 394 nm. CIE color coordinates (x, y) exposed red emission, making this nanophosphor a potential candidate in NUV excited WLEDs.



中文翻译:

溶液燃烧法合成掺红色Eu 3+的纳米发光体的结构与光致发光研究

通过溶液燃烧法制备了Eu 3+掺杂的Ba 3 YP 3 O 12纳米颗粒。Rietveld精炼证实,该系统以I-43d(2 2 0)空间群的立方结构结晶。观察到纳米范围的球形颗粒,其有助于改善发光。宿主的4.9 eV光学带隙表明,它是镧系元素活化剂的良好吸引剂。光致发光发射光谱表明,当在394 nm的波长下激发时,在612 nm的Eu 3+离子上,主要的发射峰分配给5 D 07 F 2跃迁。CIE颜色坐标(xy)暴露出红色发射光,从而使这种纳米磷光体成为NUV激发WLED中的潜在候选物。

更新日期:2020-06-26
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