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Light-Induced Excited-State Palladium Catalysis for Challenging Couplings
Chem ( IF 19.1 ) Pub Date : 2020-05-29 , DOI: 10.1016/j.chempr.2020.05.015
Zhixiong Liu , Xiang-Yu Chen

Recent work published in Science by Arndtsen and co-workers reports a novel excited-state palladium-catalyzed carbonylation. The key to success was both oxidative addition and reductive elimination steps accelerated by visible light, which allowed challenging aryl or alkyl halides and difficult nucleophiles as reaction partners.



中文翻译:

光诱导激发态钯催化性极强的联轴器

Arndtsen及其同事在《科学》杂志上发表的最新著作报道了一种新型的激发态钯催化的羰基化反应。成功的关键是可见光加速了氧化加成和还原消除步骤,这使具有挑战性的芳基或烷基卤化物和困难的亲核试剂成为反应伙伴。

更新日期:2020-05-29
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