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Domino ring opening and selective O/S-alkylation of cyclic ethers and thioethers.
Molecular Diversity ( IF 2.013 ) Pub Date : 2020-05-27 , DOI: 10.1007/s11030-020-10105-2
Manickam Bakthadoss,Vishal Agarwal,Thirupathi Reddy Tadiparthi,Mushaf Mohammad

Abstract Chemoselective domino ring opening and selective O/S-alkylation of ethers/thioethers over enol C/O alkylation has been observed. Various 2-aryl chromanones/thiochromanones with alkyl/allyl bromides were smoothly converted into the corresponding highly functionalized ethers and thioethers in excellent yields with high selectivity. Graphic abstract An unusual, chemoselective domino ring opening and selective ether/thioether O/S-alkylation over. An unusual, chemoselective domino ring opening and selective ether/thioether O/S alkylation over enol C/O alkylation has been observed.
更新日期:2020-05-27

 

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