3d metallaelectrocatalysis for resource economical syntheses.,Chemical Society Reviews

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3d metallaelectrocatalysis for resource economical syntheses.
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2020-05-27 , DOI: 10.1039/d0cs00149j
Parthasarathy Gandeepan ₁ , Lars H Finger ₂ , Tjark H Meyer ₂ , Lutz Ackermann ₃

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Resource economy constitutes one of the key challenges for researchers and practitioners in academia and industries, in terms of rising demand for sustainable and green synthetic methodology. To achieve ideal levels of resource economy in molecular syntheses, novel avenues are required, which include, but are not limited to the use of naturally abundant, renewable feedstocks, solvents, metal catalysts, energy, and redox reagents. In this context, electrosyntheses create the unique possibility to replace stoichiometric amounts of oxidizing or reducing reagents as well as electron transfer events by electric current. Particularly, the merger of Earth-abundant 3d metal catalysis and electrooxidation has recently been recognized as an increasingly viable strategy to forge challenging C–C and C–heteroatom bonds for complex organic molecules in a sustainable fashion under mild reaction conditions. In this review, we highlight the key developments in 3d metallaelectrocatalysis in the context of resource economy in molecular syntheses until February 2020.

中文翻译：

资源经济性合成的3d金属电化学催化。

就对可持续和绿色合成方法的需求不断增长而言，资源经济是学术界和工业界研究人员和从业人员面临的主要挑战之一。为了在分子合成中达到理想的资源经济水平，需要新的途径，包括但不限于使用天然丰富的可再生原料，溶剂，金属催化剂，能源和氧化还原试剂。在这种情况下，电合成产生了用电流代替化学计量的氧化或还原试剂以及电子转移事件的独特可能性。尤其，最近，人们已经认识到，地球上丰富的3d金属催化和电氧化的合并是在温和的反应条件下以可持续的方式为复杂的有机分子建立具有挑战性的C-C和C-杂原子键的越来越可行的策略。在这篇综述中，我们重点介绍了分子合成中资源经济背景下3d金属电化学催化的关键进展，直到2020年2月。

更新日期：2020-07-06

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