The force of MOFs: the potential of switchable metal-organic frameworks as solvent stimulated actuators.,Chemical Communications

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The force of MOFs: the potential of switchable metal-organic frameworks as solvent stimulated actuators.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-05-27 , DOI: 10.1039/d0cc02505d
Pascal Freund ₁ , Irena Senkovska , Bin Zheng , Volodymyr Bon , Beate Krause , Guillaume Maurin , Stefan Kaskel

Affiliation

We evaluate experimentally the force exerted by flexible metal–organic frameworks through expansion for a representative model system, namely MIL-53(Al). The results obtained are compared with data collected from intrusion experiments while molecular simulations are performed to shed light on the re-opening of the guest-loaded structure. The critical impact of the transition stimulating medium on the magnitude of the expansion force is demonstrated.

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