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The force of MOFs: the potential of switchable metal-organic frameworks as solvent stimulated actuators.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-05-27 , DOI: 10.1039/d0cc02505d
Pascal Freund 1 , Irena Senkovska , Bin Zheng , Volodymyr Bon , Beate Krause , Guillaume Maurin , Stefan Kaskel
Affiliation  

We evaluate experimentally the force exerted by flexible metal–organic frameworks through expansion for a representative model system, namely MIL-53(Al). The results obtained are compared with data collected from intrusion experiments while molecular simulations are performed to shed light on the re-opening of the guest-loaded structure. The critical impact of the transition stimulating medium on the magnitude of the expansion force is demonstrated.

中文翻译:

MOF的作用力:可切换的金属有机框架作为溶剂刺激致动器的潜力。

我们通过实验评估弹性金属有机框架通过扩展代表性模型系统MIL-53(Al)施加的力。将获得的结果与从入侵实验收集的数据进行比较,同时进行分子模拟以阐明客座结构的重新开放。证明了过渡刺激介质对膨胀力大小的关键影响。
更新日期:2020-07-07
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