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Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine-dioxime catalysts under both aqueous and organic conditions.
Chemical Communications ( IF 4.9 ) Pub Date : 2020-05-27 , DOI: 10.1039/d0cc02604b
Chun-Leung Kwok 1 , Shun-Cheung Cheng , Pui-Yu Ho , Shek-Man Yiu , Wai-Lun Man , Vonika Ka-Man Au , Po-Keung Tsang , Chi-Fai Leung , Chi-Chiu Ko , Marc Robert
Affiliation  

The photocatalytic generation of an NADH synthetic analogue, i.e. 1-benzyl-1,4-dihydronicotinamide (1,4-BNAH), has been studied using the cobalt diimino–dioxime complexes and the BF2-bridged derivative as catalysts. 1,4-BNAH was produced in both aqueous and organic media at unprecedented turnover numbers with metal and organic photosensitizers, respectively.

中文翻译:

在含水和有机条件下,使用钴二亚胺-二肟催化剂,可以无贵金属地光催化生产NADH类似物。

使用钴二亚氨基-二肟配合物和BF 2-桥联衍生物作为催化剂,研究了NADH合成类似物(1-苄基-1,4-二氢烟酰胺(1,4-BNAH))的光催化生成。金属和有机光敏剂分别在水和有机介质中以空前的营业额生产了1,4-BNAH。
更新日期:2020-07-07
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