The Suzuki–Miyaura Cross‐Coupling as the Key Step in the Synthesis of 2‐Aminobiphenyls and 2,2'‐Diaminobiphenyls: Application in the Synthesis of Schiff Base Complexes of Zn,European Journal of Organic Chemistry

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The Suzuki–Miyaura Cross‐Coupling as the Key Step in the Synthesis of 2‐Aminobiphenyls and 2,2'‐Diaminobiphenyls: Application in the Synthesis of Schiff Base Complexes of Zn
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2020-05-27 , DOI: 10.1002/ejoc.202000599
Knut Tormodssønn Hylland ₁ , Sigurd Øien-Ødegaard ₁ , Mats Tilset ₁

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The Suzuki–Miyaura reaction is used as a key step for the synthesis of 2‐aminobiphenyls and 2,2'‐diaminobiphenyls, which in turn can be utilized to make Schiff base complexes of Zn. Special emphasis is on the cross‐coupling reaction between 2‐bromoanilines and a 2‐nitro‐substituted arylboronic acid, for which there is little existing precedence.

中文翻译：

Suzuki-Miyaura交叉偶联是2-氨基联苯和2,2'-二氨基联苯合成的关键步骤：在Zn席夫碱配合物合成中的应用

Suzuki-Miyaura反应被用作合成2-氨基联苯和2,2'-二氨基联苯的关键步骤，而这些反过来又可用于制备Zn的席夫碱配合物。特别强调的是2-溴苯胺与2-硝基取代的芳基硼酸之间的交叉偶联反应，目前尚无此类研究。

更新日期：2020-07-16

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