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Challenges and opportunities for manganese oxides in low-temperature selective catalytic reduction of NOx with NH3: H2O resistance ability
Journal of Solid State Chemistry ( IF 3.2 ) Pub Date : 2020-05-27 , DOI: 10.1016/j.jssc.2020.121464
Ningqiang Zhang , Hong He , Dingsheng Wang , Yadong Li

Manganese oxides (MnOx) have attracted increasing attention in selective catalytic reduction of NOx with NH3 (NH3-SCR) due to their excellent low-temperature catalytic activities. However, MnOx still suffer from poor resistance to SO2 and H2O in NH3-SCR. In particular, the irreversible poisoning of SO2 limits their practical applications in NH3-SCR. With the new regulations concerning the emission of SO2 gas, MnOx may be used for control over NOx (i.e. NO and NO2) emission in NH3-SCR. This mini-review was devoted to challenges and opportunities of MnOx catalysts in NH3-SCR, which may be helpful for its practical application in NH3-SCR system.



中文翻译:

挑战和机遇为锰的氧化物在低温选择性催化还原NO的X与NH 3:H 2 ö电阻能力

锰氧化物(MnO x)由于具有出色的低温催化活性,因此在用NH 3(NH 3 -SCR)选择性催化还原NO x方面引起了越来越多的关注。然而,在NH 3 -SCR中,MnO x仍然具有对SO 2和H 2 O的不良耐受性。特别地,SO 2的不可逆中毒限制了它们在NH 3 -SCR中的实际应用。根据有关SO 2气体排放的新规定,MnO x可以用于控制NH中的NO x(即NO和NO 2)排放3 -SCR。这篇小型综述专门探讨了Mn 3 x催化剂在NH 3 -SCR中的挑战和机遇,这可能有助于其在NH 3 -SCR系统中的实际应用。

更新日期:2020-06-27
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