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Synthesis and Crystal Structure of a Cobalt Coordination Polymer Based on Bis(4-(1 H -imidazol-1-YL)phenyl)methanone and trans -1,2-Cyclohexanedicarboxylate
Crystallography Reports ( IF 0.6 ) Pub Date : 2020-05-27 , DOI: 10.1134/s1063774520030347 G.-F. Wang , S.-W. Sun , Y.-P. Tang , Y.-F. Zhao , B.-H. Wei , L.-X. Meng , Y.-D. Zhu
中文翻译:
基于双(4-(1 H-咪唑-1-基)苯基)甲酮和反式-1,2-环己烷二甲酸钴的钴配位聚合物的合成和晶体结构
更新日期:2020-05-27
Crystallography Reports ( IF 0.6 ) Pub Date : 2020-05-27 , DOI: 10.1134/s1063774520030347 G.-F. Wang , S.-W. Sun , Y.-P. Tang , Y.-F. Zhao , B.-H. Wei , L.-X. Meng , Y.-D. Zhu
Abstract
A cobalt coordination polymer with V-shaped ligands, {[L1Co(trans-CHDCA)] · 2H2O}n (L1 = bis(4-(1H-imidazol-1-yl)phenyl)methanone, trans-H2CHDCA = trans-1,2-cyclohexanedicarboxylic acid) has been synthesized under solvothermal conditions. It has been characterized by IR spectra, elemental analyses and single-crystal X-ray diffraction. The crystal is monoclinic, sp. gr. P21/c, Z = 4. In crystal, trans-CHDCA2– ions bridge Co atoms into wave-like chain along the c-axis. Furthermore, chains are linked by bis(4-(1H-imidazol-1-yl)phenyl)methanone to form 2D layers.中文翻译:
基于双(4-(1 H-咪唑-1-基)苯基)甲酮和反式-1,2-环己烷二甲酸钴的钴配位聚合物的合成和晶体结构