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Efficient and Tunable White-Light Emission Using a Dispersible Porous Polymer.
Macromolecular Rapid Communications ( IF 4.2 ) Pub Date : 2020-05-25 , DOI: 10.1002/marc.202000176
Alex M James 1 , Robert Dawson 1
Affiliation  

A dispersible porous polymer (PEG113b ‐DVB800co ‐AA200) based on the controlled radical polymerization of divinylbenzene and acrylic acid with a poly(ethylene glycol) (PEG) macrochain transfer agent (macro‐CTA) is synthesized and postsynthetically modified with anthracene. This blue‐emitting porous polymer is used to encapsulate the yellow‐emitting fluorophore rhodamine B into its core, resulting in a white‐light emitting dispersion with a quantum yield of 38% and commission internationale de l’éclairage coordinates of (X = 0.33, Y = 0.32).

中文翻译:

使用分散性多孔聚合物的高效可调谐白光发射。

可分散的多孔聚合物(PEG 113 - b -DVB 800 --AA 200)的基础上与聚(乙二醇)二乙烯基苯和丙烯酸的受控的自由基聚合(PEG)macrochain转移剂(宏CTA)被合成并用蒽进行后期合成。这种发蓝色光的多孔聚合物用于将发黄光的荧光染料若丹明B包裹到其芯中,从而产生发白色光的分散体,其量子产率为38%,国际佣金坐标为(X = 0.33,Y = 0.32)。
更新日期:2020-06-18
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