Abstract Heat capacity of selected series of ionic liquids was predicted by means of several group contribution models of ionic liquid and compared with available experimental data. The examined series of ionic liquids were with methylimidazolium, menthoxymethyl imidazolium and ethoxyethoxyethyl imidazolium cations with different alkyl substituents, while the anions were the saccharinate or bistriflate. All data, experimental and predicted, were analyzed by means of mathematical gnostics and critically evaluated. Based on the thermodynamics of data and theory of measurement, mathematical gnostics is a novel non-statistical approach towards data uncertainty.

中文翻译：

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离子液体热容预测方法与选定实验数据的高级数据分析比较

摘要 利用离子液体的几种组贡献模型预测了选定系列离子液体的热容量，并与现有的实验数据进行了比较。所研究的离子液体系列是具有不同烷基取代基的甲基咪唑鎓、薄荷氧基甲基咪唑鎓和乙氧基乙氧基乙基咪唑鎓阳离子，而阴离子是糖精酸盐或双氟甲磺酸盐。所有数据，无论是实验数据还是预测数据，都通过数学知识进行了分析和批判性评估。基于数据的热力学和测量理论，数学 gnostics 是一种针对数据不确定性的新型非统计方法。