Developing solid materials with high CO₂ adsorption capacity and catalytic activity has been a hotspot due to the greenhouse effect. In this work, bi-functionalized ionic liquid 1-vinyl-3-methoxyethyl imidazolium glycinate ([VMOEim][Gly]) was copolymerized with crosslinker divinylbenzene (DVB) to obtain bi-functionalized ionic liquid porous copolymers P(nDVB-[VMOEim][Gly]) and HP(nDVB-[VMOEim][Gly]). These copolymers possess loose stack of small particles or laminates, and they contain mesopores and a small number of micropores. For HP(0.6DVB-[VMOEim][Gly]), surface area reaches up to 508 m²·g⁻¹ and the initial decomposition temperature is about 180 °C. Then these porous copolymers were applied for CO₂ adsorption at 25 °C and cycloaddition reaction of CO₂ with epichlorohydrin under ambient pressure and cocatalyst-free condition. The maximum CO₂ capture capacity is 64.5 mg/g with HP(0.6DVB-[VMOEim][Gly]) as adsorbent. The effects of catalyst type, catalyst dosage, reaction time and temperature on the yield of cyclic carbonate were also investigated. The optimum conditions are 4 wt% of HP(0.6DVB-[VMOEim][Gly]) (based on the epichlorohydrin) as catalyst at 130 °C for 10 h, and the yield of 4-(chloromethyl)-1,3-dioxolan-2-one can reach 94%. Furthermore, the catalytic activity of HP(0.6DVB-[VMOEim][Gly]) maintains and the yield is 91% after five-cycle experiment. The mechanism of cycloaddition reaction was also discussed.

由于温室效应，开发具有高CO ₂吸附能力和催化活性的固体材料已成为热点。在这项工作中，将双官能化离子液体1-乙烯基-3-甲氧基乙基咪唑鎓甘氨酸盐（[VMOEim] [Gly]）与交联剂二乙烯基苯（DVB）共聚，以获得双官能化离子液体多孔共聚物P（n DVB- [VMOEim ] [Gly]）和HP（n DVB- [VMOEim] [Gly]）。这些共聚物具有小颗粒或叠层的松散堆叠，并且它们包含中孔和少量的微孔。对于HP（0.6DVB- [VMOEim] [Gly]），表面积达到508 m ² ·g ^-1，初始分解温度约为180°C。然后将这些多孔共聚物用于CO₂在25°C下吸附，在常压和无助催化剂条件下，CO ₂与环氧氯丙烷的环加成反应。以HP（0.6DVB- [VMOEim] [Gly]）为吸附剂，最大CO ₂捕集能力为64.5 mg / g。还研究了催化剂类型，催化剂用量，反应时间和温度对环状碳酸酯收率的影响。最佳条件是在130°C下10 h制备4 wt％的HP（0.6DVB- [VMOEim] [Gly]）（基于环氧氯丙烷）催化剂，并获得4-（氯甲基）-1,3- dioxolan-2-one可以达到94％。此外，经过五次循环实验，HP（0.6DVB- [VMOEim] [Gly]）的催化活性得以维持，产率为91％。还讨论了环加成反应的机理。