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A comparative study of arsenic(V), tetracycline and nitrate ions adsorption onto magnetic biochars and activated carbon
Chemical Engineering Research and Design ( IF 3.9 ) Pub Date : 2020-05-23 , DOI: 10.1016/j.cherd.2020.05.011
Guangcai Tan , Yi Mao , Hongyuan Wang , Nan Xu

The removal of contaminants in co-solute systems is a pressing issue. Herein, the adsorption capacities of magnetic biochars and activated carbon were investigated and compared for various aqueous anions, including As(V), tetracycline (TC) and NO3, existed alone or as a mixture. One-step (pre-treating biomass with FeCl3 before pyrolysis (FB)) and two-step (pyrolysing biomass before modification with FeCl3 (BF)) magnetization methods were applied to synthesize magnetic biochars. Magnetic activated carbon (AF) was also prepared with the two-step magnetization method. FB presented the highest adsorption capacities for As(V) and NO3 respectively at 6.77 and 6.31 mg g−1. AC (612.38 mg g−1) showed the highest adsorption capacity for TC, which decreased by 189.76% after magnetization. Magnetization was proved to be a promising method to improve the adsorption of both As(V) and NO3 on adsorbents through enhanced electrostatic attraction, while the adsorption of TC depended mainly on high specific surface area of the adsorbent. Results from competitive adsorption in the co-solute systems suggested that FB had a great potential for application in the co-contaminated environment (heavy metal and inorganic anions), and AF could be a promising adsorbent to remediate multiple-contaminated environment (i.e. organic pollution and heavy metal/inorganic anions).



中文翻译:

磁性生物炭和活性炭吸附砷(V),四环素和硝酸根离子的比较研究

在共溶体系中去除污染物是一个紧迫的问题。在此,磁性生物炭和活性炭的吸附能力进行了研究,并用于各种含水阴离子,包括随着(V),四环素(TC)和NO相比3 - ,存在单独使用或作为混合物使用。采用一步法(热解(FB)前用FeCl 3预处理生物质)和两步法(FeCl 3改性(BF)前将生物质热解)磁化法合成磁性生物炭。还通过两步磁化方法制备了磁性活性炭(AF)。FB呈现最高吸附容量为的As(V)和NO 3 -分别在6.77和6.31毫克克-1。AC(612.38 mg g -1)对TC表现出最高的吸附能力,在磁化后下降了189.76%。磁化被证明是改善两者的As(V)和NO的吸附有希望的方法3 -上通过增强静电引力的吸附剂,而TC的吸附主要取决于吸附剂的高比表面积。共溶体系中竞争性吸附的结果表明,FB在共污染环境(重金属和无机阴离子)中具有巨大的应用潜力,AF可能是有望修复多污染环境(即有机污染)的吸附剂和重金属/无机阴离子)。

更新日期:2020-05-23
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