Catalysis Communications ( IF 3.4 ) Pub Date : 2020-05-23 , DOI: 10.1016/j.catcom.2020.106058 Surachai Karnjanakom , Panya Maneechakr , Chanatip Samart , Suwadee Kongparakul , Guoqing Guan , Asep Bayu
The direct synthesis of ethyl levulinate (EL) from sucrose was investigated under co-solvent of tetrahydrofuran (THF)/ethanol over stable/active heterogeneous acid catalyst. Several Lewis acid-metal oxides were doped onto Brønsted acid-sulfonated carbon (SC) and the results found that Zn-SC exhibited highest activity for production of EL from sucrose conversion of 100% with a selectivity of 72.1%. The catalytic mechanism for conversion of sucrose into EL and other products was investigated through significant effects such as catalyst type, co-solvent and ultrasonic application. The catalyst reusability test exhibited high stability for five cycles and then dramatically decreased without any regeneration process.
中文翻译:
共溶剂体系下选择性多相酸催化糖直接转化为乙酰丙酸乙酯
在四氢呋喃(THF)/乙醇共溶剂/稳定/活性多相酸催化剂上,研究了由蔗糖直接合成乙酰丙酸乙酯(EL)的方法。几种路易斯酸金属氧化物被掺杂到布朗斯台德酸磺化碳(SC)上,结果发现Zn-SC对蔗糖转化率100%的EL生产EL的活性最高,选择性为72.1%。通过诸如催化剂类型,助溶剂和超声应用等显着作用,研究了将蔗糖转化为EL和其他产物的催化机理。催化剂可重复使用性测试显示了五个循环的高稳定性,然后在没有任何再生过程的情况下急剧降低。