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Specific features of the formation, catalytic activity, and corrosion stability of PdCu electrolytic co-deposit
Journal of Solid State Electrochemistry ( IF 2.6 ) Pub Date : 2020-05-24 , DOI: 10.1007/s10008-020-04612-3
Boris I. Podlovchenko , Tatyana D. Gladysheva , Yurii M. Maksimov , Dmitry S. Volkov , Konstantin I. Maslakov

A mixed electrolytic deposit (ED) of PdCu (~20 at.% Cu) is synthesized from a solution of 1 mМ PdSO4 + 5 mМ CuSO4 + 0.5 M H2SO4 in the region of copper underpotential deposition (+400 mV vs. RHE). The incorporation of copper into the Pd deposit increases its true surface area (Strue) by a factor of ~20 and changes its hydrogen sorption characteristics. The ED PdCu demonstrates higher specific activity in FAOR as compared with individual Pd deposit (Еdep = 0.4 V). The specific solubility of Pd from ED PdCu is shown to be 2–3 times lower than the solubility of ED Pd; however, its total solubility from PdCu increases due to the strong increase in Strue.



中文翻译:

PdCu电解共沉积的形成,催化活性和腐蚀稳定性的特定特征

由1mМPdSO 4  + 5mМCuSO 4  + 0.5 MH 2 SO 4溶液在铜的欠电位沉积区域(+400 mV vs. )合成PdCu(〜20 at。%Cu)的混合电解沉积物(ED)(RHE)。将铜掺入Pd沉积物中时,其真实表面积(S true)增大了约20倍,并改变了其氢吸附特性。的ED PDCU在FAOR表明更高的比活性与个别的Pd存款(相比Е DEP  =  0.4 V)。ED PdCu的Pd的比溶解度比ED Pd的溶解度低2-3倍。但是,由于PdCu的强烈增加,其在PdCu中的总溶解度增加Š

更新日期:2020-05-24
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