Controlled Release of Reactive Gases: A Tale of Taming Carbon Monoxide.,ChemPlusChem

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Controlled Release of Reactive Gases: A Tale of Taming Carbon Monoxide.
ChemPlusChem ( IF 3.0 ) Pub Date : 2020-05-22 , DOI: 10.1002/cplu.202000319
Anne K Ravn ₁ , Martin B Johansen _{1,

2} , Troels Skrydstrup ₁

Affiliation

This Personal Account describes the development of air‐stable and solid precursors for on‐demand release of carbon monoxide. In combination with the development of a two‐chamber reactor, COware®, CO liberation can be achieved under safe working conditions, as well as allowing transition metal‐mediated carbonylations with stoichiometric carbon monoxide. Particularly appealing is the adaptability of this chemical technology for the preparation of carbon isotope labeled bioactive compounds.

中文翻译：

活性气体的控制释放：驯服一氧化碳的故事。

此个人帐户介绍了用于按需释放一氧化碳的空气稳定和固体前体的开发。结合开发两室反应器COware®，可以在安全的工作条件下实现CO的释放，并允许化学计量的一氧化碳进行过渡金属介导的羰基化。特别吸引人的是该化学技术对制备碳同位素标记的生物活性化合物的适应性。

更新日期：2020-07-15

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