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Analysis of 210Po, 210Bi, and 210Pb in atmospheric and oceanic samples by simultaneously auto-plating 210Po and 210Bi onto a nickel disc.
Journal of Environmental Radioactivity ( IF 1.9 ) Pub Date : 2020-05-21 , DOI: 10.1016/j.jenvrad.2020.106301
Qiangqiang Zhong 1 , Viena Puigcorbé 2 , Christian Sanders 3 , Jinzhou Du 1
Affiliation  

210Po and 210Pb are commonly measured to study particle cycling and particulate organic carbon export (POC) flux from the upper ocean. 210Bi is a potential oceanographic tracer. However, no convenient and rapid analytical method for 210Bi has been developed in the marine environment due to its short half-life (5 days). The aims are to study factors influencing the simultaneous auto-plating of 210Po and 210Bi onto nickel disc and to develop an effective ship-board procedure for the rapid measurement of 210Po, 210Bi, and 210 Pb at sea. The results suggest that the optimal conditions for auto-deposition of 210Po and 210Bi were achieved by using a 25 mm diameter nickel disc in 60 mL acidic solution (pH = 0.5) for 16 h at 25 ± 1 °C. By adding 209Po and 207Bi as yield tracers to the sediments, recoveries of Po and Bi were >90%. If 210Po or 210Bi were in equilibrium with 210Pb, 210Po and 210Bi could also be potential proxies for 210Pb in sedimentary chronology. The overall recoveries of 209Po and 207Bi were >70% for rainwaters and >60% for seawater samples, respectively, which indicates this analytical procedure is also applicable to marine and atmospheric environments. This method allows the rapid measurement of 210Bi on a ship and help to obtain its vertical profile or spatial distribution in the marine environment within 1–2 days.



中文翻译:

通过同时自动将210Po和210Bi电镀到镍盘上,分析大气和海洋样品中的210Po,210Bi和210Pb。

通常测量210 Po和210 Pb来研究来自上层海洋的颗粒循环和颗粒有机碳出口(POC)通量。210 Bi是潜在的海洋示踪剂。但是,由于其半衰期短(5天),因此尚未在海洋环境中开发出方便快捷的210 Bi分析方法。目的是研究影响210 Po和210 Bi同时自动电镀到镍片上的因素,并开发一种有效的船上程序,以在海上快速测量210 Po,210 Bi和210 Pb。结果表明自动沉积的最佳条件通过在25±1°C的条件下,使用直径为25 mm的镍圆盘在60 mL酸性溶液(pH = 0.5)中放置16 h,可以达到210 Po和210 Bi。通过向沉积物中添加209 Po和207 Bi作为产量示踪剂,Po和Bi的回收率> 90%。如果210 Po或210 Bi与210 Pb处于平衡状态,那么在沉积年代学中210 Po和210 Bi也可能是210 Pb的潜在代表。209 Po和207的总回收率雨水的Bi分别> 70%,海水样品的Bi> 60%,这表明该分析程序也适用于海洋和大气环境。这种方法可以快速测量船上的210 Bi,并在1-2天内获得其在海洋环境中的垂直剖面或空间分布。

更新日期:2020-05-21
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