In this study, p(AAm-co-TACYC) hydrogels were synthesized using TACYC crosslinker. The p(AAm-co-TACYC) hydrogel was used for preparation of Cu(0) nanoparticles as support material. The p(AAm-co-TACYC)@Cu was prepared by chemical reduction of Cu²⁺ ions in the p(AAm-co-TACYC) networks and was structurally characterized in detail. Later the catalytic activity of p(AAm-co-TACYC)@Cu was investigated for hydrogen production from AB and EDAB hydrolysis. Detailed kinetic studies were performed for both hydrogen storage materials. The p(AAm-co-TACYC)@Cu was a more active catalyst for the EDAB hydrolysis reaction. The E_a values of p(AAm-co-TACYC)@Cu for the AB and EDAB hydrolysis reactions were determined as 68.36 kJ mol⁻¹ and 39.07 kJ mol⁻¹, respectively. In addition to the perfect catalytic activity of p(AAm-co-TACYC)@Cu, it had good reusability. After ten consecutive uses for AB and EDAB hydrolysis, the p(AAm-co-TACYC)@Cu still had 88% and 85% of initial activity, respectively.

在这项研究中，使用TACYC交联剂合成了p（AAm-co-TACYC）水凝胶。p（AAm-co-TACYC）水凝胶用于制备Cu（0）纳米粒子作为载体材料。通过化学还原p（AAm-co-TACYC）网络中的Cu ²⁺离子制备p（AAm-co-TACYC）@Cu，并对其结构进行了详细表征。随后研究了p（AAm-co-TACYC）@Cu的催化活性，以研究AB和EDAB水解产生的氢。对两种储氢材料都进行了详细的动力学研究。p（AAm-co-TACYC）@Cu是用于EDAB水解反应的更具活性的催化剂。确定AB和EDAB水解反应的p（AAm-co-TACYC）@Cu的E _a值为68.36 kJ mol ^-1和39.07 kJ mol ^-1， 分别。p（AAm-co-TACYC）@Cu具有完美的催化活性，并且具有良好的可重复使用性。在AB和EDAB水解连续使用十次后，p（AAm-co-TACYC）@Cu仍然分别具有88％和85％的初始活性。