Biobased Poly(ethylene 2,5-furancoate): No Longer an Alternative, but an Irreplaceable Polyester in the Polymer Industry,ACS Sustainable Chemistry & Engineering

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Biobased Poly(ethylene 2,5-furancoate): No Longer an Alternative, but an Irreplaceable Polyester in the Polymer Industry
ACS Sustainable Chemistry & Engineering ( IF 7.1 ) Pub Date : 2020-05-19 , DOI: 10.1021/acssuschemeng.0c01862
Xuan Fei _{1,

2,

3} , Jinggang Wang _{1,

2} , Jin Zhu _{1,

2} , Xuezhen Wang ₁ , Xiaoqing Liu _{1,

2}

Affiliation

Recently, studies on the synthesis, modification, and functionalization of polyesters derived from 2,5-furandicarboxylic acid (2,5-FDCA) have attracted widespread attention. Among them, poly(ethylene 2,5-furanoate) (PEF) has been in the spotlight due to its greener production process, higher glass transition temperature (T_g), good mechanical performance, and excellent barrier properties, which have qualified it as a new generation of packaging material to be considered for replacement of polyethylene terephthalate (PET). Currently it is a promising rising star in the field of biobased polymers, yet there has been no review entirely focused on it. This article focuses on the research related PEF, discussing its mainstream synthetic methods including optimization of catalysts with solutions of coloration and side reactions, and its comprehensive properties such as thermal, crystallization, mechanical, and barrier performances. Other aspects highlighted are modifications for better properties and the introduction of biodegradability as well as the construction of composites materials. This article aims to reveal the development path of PEF and help us to understand it more deeply and widely in a short time.

中文翻译：

生物基聚（2,5-呋喃乙烯酸酯）：不再是替代品，而是聚合物工业中不可替代的聚酯

近来，对衍生自2，5-呋喃二甲酸（2，5-FDCA）的聚酯的合成，改性和功能化的研究引起了广泛的关注。其中，聚（2,5-呋喃甲酸乙烯酯）（PEF）由于其绿色生产工艺，较高的玻璃化转变温度（T _g），良好的机械性能和出色的阻隔性能，使其成为新一代可替代聚对苯二甲酸乙二醇酯（PET）的包装材料。目前，它是生物基聚合物领域充满希望的后起之秀，但还没有完全针对它的评论。本文着重于与PEF相关的研究，讨论了PEF的主流合成方法，包括通过着色和副反应溶液优化催化剂，以及其综合性质，如热，结晶，机械和阻隔性能。强调的其他方面是为获得更好的性能而进行的修改，以及引入了生物可降解性以及复合材料的构造。

更新日期：2020-05-19

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