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Solution-phase growth of tin oxide (SnO2) nanostructures: Structural, optical and photocatalytic properties
Materials Science and Engineering: B ( IF 3.9 ) Pub Date : 2020-05-19 , DOI: 10.1016/j.mseb.2020.114568
Hasan Mahmood , M.A. Khan , Bilal Mohuddin , Tariq Iqbal

Tin dioxide (SnO2) nanostructures have been synthesized successfully via solution phase growth technique. Effect of reaction temperature, time and surfactant on morphology, size and bandgap has been studied. The rods, flowers, and spheres like morphologies of SnO2 have been observed using Scanning Electron Microscopy (SEM). Structural analysis of synthesized SnO2 has been carried out by X-Ray Diffraction (XRD). XRD peaks revealed the tetragonal structure of SnO2 nanocrystals. The increase in grain size was observed with an increase in reaction time and reaction temperature of the synthesis process. Fourier Transform Infrared Spectroscopy (FTIR) has been employed to study the vibrational modes. Optical properties of the SnO2 nanostructures have also been studied by UV–vis spectroscopy. The energy bandgap of the as-prepared SnO2 nanocrystals were estimated between 3.76 eV and 4.05 eV. Photocatalytic activities of SnO2 nanostructures were studied on Rhodamine B (Rhd B) dye under solar light illumination. Approximately 91% degradation of Rhd B was observed with as-synthesized SnO2 nanostructures.



中文翻译:

溶液相生长氧化锡(SnO 2)纳米结构:结构,光学和光催化性能

通过溶液相生长技术已经成功地合成了二氧化锡(SnO 2)纳米结构。研究了反应温度,时间和表面活性剂对形态,尺寸和带隙的影响。使用扫描电子显微镜(SEM)已经观察到棒状,花状和球形如SnO 2的形态。合成的SnO 2的结构分析已通过X射线衍射(XRD)进行。XRD峰揭示了SnO 2纳米晶体的四方结构。随着合成过程的反应时间和反应温度的增加,观察到晶粒尺寸的增加。傅里叶变换红外光谱(FTIR)已用于研究振动模式。SnO的光学性质还通过紫外可见光谱研究了2种纳米结构。所制备的SnO 2纳米晶体的能带隙估计在3.76 eV和4.05 eV之间。研究了若丹明B(Rhd B)染料在太阳光下对SnO2纳米结构的光催化活性。合成后的SnO 2纳米结构观察到Rhd B降解约91%。

更新日期:2020-05-19
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