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Hydrothermal carbonization of the filter bed remained after filtration of olive mill wastewater on olive stones for biofuel application
Biomass Conversion and Biorefinery ( IF 4 ) Pub Date : 2020-05-20 , DOI: 10.1007/s13399-020-00743-9
Ghizlane Enaime , Abdelaziz Baçaoui , Abdelrani Yaacoubi , Marc Wichern , Manfred Lübken

In the present study, the olive stones (OS) filter bed used for the filtration of olive mill wastewater (OMWW), named OMWW/OS-FR, was converted via hydrothermal carbonization (HTC) into solid biofuel. HTC was operated at three different temperatures (180, 240, and 300 °C) and the chemical and combustible characteristics of the produced hydrochars were investigated. The hydrochars prepared at 240 and 300 °C HTC temperatures exhibited high carbon recovery (80.1–84.2%) and fixed carbon content (45.8–46.8%), reduced volatile matter concentration (49.9–52.2%), low hydrogen to carbon (H/C) and oxygen to carbon (O/C) ratios (0.91–0.98 and 0.18–0.22, respectively) and high heating value (29.7–31 MJ/kg). The characteristics of the HTC-hydrochars were compared to those of biochar prepared by low temperature pyrolysis (LTP) at 400 °C. The results highlighted the improved fuel properties of HTC-hydrochars as compared to those of LTP-biochar in term of energy yield and energy content; this indicates the adaptability of HTC for OMWW/OS-FR upgrading. The temperature of 240 °C was selected as the optimal HTC temperature for the production of hydrochar with enhanced biofuel properties and with lower energy consumption for the thermal treatment of the water contained in the OMWW/OS-FR. Consequently, the use of HTC at 240 °C instead of dry LTP allowed for an energy saving over 49%. Accordingly, it can be concluded that HTC, in term of energy consumption, is more appropriate than LTP to manage the moisture in the OMWW/OS-FR.



中文翻译:

在将橄榄磨机废水过滤到用于生物燃料的橄榄石上后,滤床的水热碳化仍然存在

在本研究中,用于橄榄厂废水(OMWW)过滤的橄榄石(OS)滤床,称为OMWW / OS-FR,通过水热碳化(HTC)转化为固体生物燃料。HTC在三种不同的温度(180、240和300°C)下运行,并研究了所生产烃的化学和可燃特性。在240和300°C的HTC温度下制备的碳氢化合物显示出高的碳回收率(80.1–84.2%)和固定的碳含量(45.8–46.8%),降低的挥发性物质浓度(49.9–52.2%),低氢到碳(H / C)和氧碳(O / C)比(分别为0.91-0.98和0.18-0.22)和高发热量(29.7-31 MJ / kg)。将HTC碳氢化合物的特性与通过400°C低温热解(LTP)制备的生物碳的特性进行了比较。结果表明,与LTP生物炭相比,HTC碳氢燃料在燃料产量和能量含量方面的燃料特性有所改善。这表明HTC对于OMWW / OS-FR升级的适应性。选择240°C作为HTC的最佳HTC温度,以生产具有增强的生物燃料特性和较低的能耗的水煤油,以进行OMWW / OS-FR中所含水的热处理。因此,使用240°C的HTC代替干燥的LTP可节省49%以上的能源。因此,可以得出结论,就能耗而言,HTC比LTP更适合管理OMWW / OS-FR中的水分。这表明HTC对于OMWW / OS-FR升级的适应性。选择240°C作为HTC的最佳HTC温度,以生产具有增强的生物燃料特性和较低的能耗的水煤油,以进行OMWW / OS-FR中所含水的热处理。因此,使用240°C的HTC代替干燥的LTP可节省49%以上的能源。因此,可以得出结论,就能耗而言,HTC比LTP更适合管理OMWW / OS-FR中的水分。这表明HTC对于OMWW / OS-FR升级的适应性。选择240°C作为HTC的最佳HTC温度,以生产具有增强的生物燃料特性和较低的能耗的水煤油,以进行OMWW / OS-FR中所含水的热处理。因此,使用240°C的HTC代替干燥的LTP可节省49%以上的能源。因此,可以得出结论,就能耗而言,HTC比LTP更适合管理OMWW / OS-FR中的水分。使用240°C的HTC代替干燥的LTP可节省49%以上的能源。因此,可以得出结论,就能耗而言,HTC比LTP更适合管理OMWW / OS-FR中的水分。使用240°C的HTC代替干燥的LTP可节省49%以上的能源。因此,可以得出结论,就能耗而言,HTC比LTP更适合管理OMWW / OS-FR中的水分。

更新日期:2020-05-20
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