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Efficient Occlusion of Nanoparticles within Inorganic Single Crystals.
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2020-05-18 , DOI: 10.1021/acs.accounts.0c00103
Yin Ning 1 , Steven P Armes 1
Affiliation  

In principle, the incorporation of guest nanoparticles within host crystals should provide a straightforward and versatile route to a wide range of nanocomposite materials. However, crystallization normally involves expelling impurities, so nanoparticle occlusion is both counter-intuitive and technically challenging. Clearly, the nanoparticles should have a strong interaction with the growing crystalline lattice, but quantifying such an affinity has been challenging; the basic principles that govern efficient nanoparticle occlusion within inorganic single crystals are rather poorly understood. In the past few years, we have focused on the elucidation of robust design rules for such systems; our progress is summarized in this article.

中文翻译:

无机单晶内纳米颗粒的有效阻塞。

原则上,客体纳米粒子在主体晶体中的掺入应为广泛的纳米复合材料提供直接且通用的途径。然而,结晶通常涉及排出杂质,因此纳米颗粒的吸附既违反直觉,又在技术上具有挑战性。显然,纳米颗粒应该与生长的晶格具有很强的相互作用,但是如何量化这种亲和力一直是一个挑战。控制无机单晶内有效纳米颗粒阻塞的基本原理还知之甚少。在过去的几年中,我们专注于阐明此类系统的稳健设计规则;本文总结了我们的进展。
更新日期:2020-05-18
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