Reactions between Diazo Compounds and Hypervalent Iodine(III) Reagents.,Angewandte Chemie International Edition

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Reactions between Diazo Compounds and Hypervalent Iodine(III) Reagents.
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2020-05-18 , DOI: 10.1002/anie.202003081
Rong Zhao ₁ , Lei Shi ₁

Affiliation

Site‐selective “cut and sew” transformations employing diazo compounds and hypervalent iodine(III) compounds involve the departure of leaving groups, a “cut” process, followed by a reorganization of the fragments by bond formation, a “sew” process. Bearing controllable cleavage sites, diazo compounds and hypervalent iodine(III) compounds play a critical role as versatile reagents in a wide range of organic transformations because their excellent nucleofugality allows for a large number of unusual reactions to occur. In recent years, the combination of diazo compounds and hypervalent iodine(III) reagents has emerged as a promising tool for developing new and valuable approaches, and has met considerable success. In this Minireview, this combination is systematically illustrated with recent advances in the field, with the aim of elaborating the synthetic utility and potential of this concept as a powerful strategy in organic synthesis.

中文翻译：

重氮化合物与高价碘（III）试剂之间的反应。

使用重氮化合物和高价碘（III）化合物的位点选择性“切割和缝合”转化涉及离去基团的离开，“切割”过程，然后通过键的形成重组片段，即“缝合”过程。重氮化合物和高价碘（III）化合物具有可控制的裂解位点，在多种有机转化中作为多功能试剂起着至关重要的作用，因为它们出色的核易性允许发生许多不同寻常的反应。近年来，重氮化合物和高价碘（III）试剂的结合已成为开发新的有价值方法的有前途的工具，并取得了相当大的成功。在本Minireview中，结合了该领域的最新进展，系统地说明了这种组合，

更新日期：2020-07-13

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