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Fourier transform CO spectra near 1.6 μm
Journal of Quantitative Spectroscopy and Radiative Transfer ( IF 2.3 ) Pub Date : 2020-05-19 , DOI: 10.1016/j.jqsrt.2020.107064
Yu.G. Borkov , A.M. Solodov , A.A. Solodov , T.M. Petrova , E.V. Karlovets , V.I. Perevalov

The absorption spectra of carbon monoxide have been recorded in the 6000–6450 cm−1 wavenumber regions using the Bruker IFS 125 HR Fourier transform spectrometer and a 30 m multipass cell with the White-type optical system. The spectra were recorded at spectral resolution of 0.008–0.012 cm−1, path length up to 1058 m, and at pressure range from 30 to 320 mbar. The temperature was about 301 K. The lines of the 3-0 bands of six isotopologues 12C16O, 13C16O, 12C18O, 12C17O, 13C18O, 13C17O and the lines of the hot 4-1 band of 12C16O were assigned in the spectra. The line intensities and the self-broadening coefficients were measured. In the case of the principal isotopologue the line intensities were determined for the lines with the angular momentum quantum number J up to 41. The effective dipole moment parameters describing the line intensities of the observed bands were fitted to the observed values of the line intensities. The uncertainty of the line intensity measurements for the strong unsaturated and unblended lines of the principal isotopologue varies between 2% and 2.5%. The comparison of our measured line intensities to those of other authors and of the HITRAN2016 database is given.



中文翻译:

1.6μm附近的傅立叶变换CO光谱

使用布鲁克IFS 125 HR傅立叶变换光谱仪和带有White型光学系统的30 m多通池,已在6000–6450 cm -1波数区域记录了一氧化碳的吸收光谱。以0.008–0.012 cm -1的光谱分辨率,长达1058 m的路径长度以及在30至320 mbar的压力范围内记录光谱。温度约为301K。六个同位素分子的3-0谱带的线为12 C 16 O,13 C 16 O,12 C 18 O,12 C 17 O,13 C 18 O,13 C 17在光谱中指定了O和12 C 16 O的4-1热带的谱线。测量线强度和自增宽系数。在主要同位素体的情况下,确定了角动量量子数J高达41的谱线的谱线强度。将描述观测带谱线强度的有效偶极矩参数与谱线强度的观测值拟合。主同位素的强不饱和线和非混合线的线强度测量不确定度在2%至2.5%之间变化。给出了我们与其他作者和HITRAN2016数据库测得的线强度的比较。

更新日期:2020-05-19
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