Auto‐Oxidative Povarov/Aromatization Tandem Reaction of Glycine Derivatives with Enamides: Acylamino as both Activating and Leaving Group,Asian Journal of Organic Chemistry

当前位置： X-MOL 学术 › Asian J. Org. Chem. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Auto‐Oxidative Povarov/Aromatization Tandem Reaction of Glycine Derivatives with Enamides: Acylamino as both Activating and Leaving Group
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-05-18 , DOI: 10.1002/ajoc.202000191
Songhai Huang ₁ , Xiazhen Bao ₁ , Ying Fu ₁ , Yongxin Zhang ₁ , Zhengjun Quan ₁ , Congde Huo ₁

Affiliation

The auto‐oxidative Povarov/aromatization tandem reaction of N‐aryl glycine derivatives with enamides yields a series of complex quinoline derivatives in good yields. The reactions are performed using only catalytic amount of Brønsted acid and O₂. The acylamino group is used as both activating and leaving group to improve the reaction efficiency in this transformation.

中文翻译：

甘氨酸衍生物与酰胺的自氧化性Povarov /芳香化串联反应：酰基氨基既是活化基团也是离去基团

N-芳基甘氨酸衍生物与酰胺的自氧化Povarov /芳香化串联反应可产生一系列复杂的喹啉衍生物，收率很高。该反应仅使用催化量的布朗斯台德酸和O _2进行。酰基氨基既用作活化基团又用作离去基团，以提高该转化反应的效率。

更新日期：2020-05-18

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11