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Synthesis and properties of novel nitro-based thermally stable energetic compounds
Defence Technology ( IF 5.0 ) Pub Date : 2020-05-18 , DOI: 10.1016/j.dt.2020.05.008
Łukasz Gutowski , Stanisław Cudziło

This paper reviews the achievements in the field of synthesis of new thermally resistant explosive compounds in the years 2009 through 2019. The performance characteristics of these compounds (sensitivity, thermal decomposition parameters, and detonation parameters) were compared with those of 1,3,5-triamino-2,4,6-trinitrobenzene, which still seems to be an unrivalled model of a thermally resistant and generally low-sensitivity explosive material. New thermally stable explosives (TSEs) were found among macromolecular compounds with tri- and dinitrophenyl groups, nitro and amine-nitro derivatives of azoles, and polynitro derivatives of calixarenes. Some of them match TATB in terms of thermal resistance and additionally have higher detonation parameters.



中文翻译:

新型基于硝基的热稳定高能化合物的合成与性能

本文回顾了2009年至2019年在新型耐热爆炸性化合物合成领域中取得的成就。将这些化合物的性能特征(灵敏度,热分解参数和爆轰参数)与1,3,5进行了比较。 -三氨基-2,4,6-三硝基苯,它似乎仍然是耐热且通常低灵敏度的爆炸材料的无与伦比的模型。在具有三和二硝基苯基基团的大分子化合物,吡咯的硝基和胺-硝基衍生物以及杯芳烃的多硝基衍生物中发现了新的热稳定炸药(TSE)。它们中的一些在热阻方面与TATB相匹配,并且还具有更高的爆轰参数。

更新日期:2020-05-18
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