This communication describes a variety of nucleophilic ring openings of N-arylated oxathiazinane heterocycles. We find that this reaction is compatible with phenoxides, naphthoxides, and thiolates and allows for the rapid assembly of N-aryl-amino ethers and N-aryl-amino thioethers. Fourteen examples are shown and a mechanistic pathway is hypothesized.

中文翻译：

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N -芳基化的恶噻嗪杂环是 1,3-氨基醚和 1,3-氨基硫醚的便捷合成子

该通讯描述了N -芳基化恶噻嗪杂环的各种亲核开环。我们发现该反应与酚盐、萘氧化物和硫醇盐相容，并允许快速组装N -芳基氨基醚和N -芳基氨基硫醚。显示了十四个示例，并假设了一个机械途径。