Journal of Central South University ( IF 4.4 ) Pub Date : 2020-05-15 , DOI: 10.1007/s11771-020-4362-6 Yun-yan Wang , Yong-jian Luo , Hui Xu , Hai-juan Xiao
The corrosion behaviors and electrochemical properties of Q235A steel in the treated water containing corrosive halide anions (F−, Cl−) have been investigated with corrosion tests of static coupon and dynamic coupon testing, electrochemical measurement of open-circuit potential and linear sweep voltammetry. The results reveal that the existence of F− and Cl− ions in the simulated treated water accelerate the corrosion rate of Q235A steel. The corrosion rate reaches maximum with F− concentration of 50 mg/L, Cl− concentration of 200 mg/L, respectively. However, Q235A steel would passivate when an applied potential is added to the system. Meanwhile, the initiating passive potential becomes positive with F−, Cl− concentration increasing. There is a little influence of F−, Cl− concentration on the initiating passivation current density. Therefore, it is necessary to control F−, Cl− concentration in the treated water when it is recycled by the pipelines made of Q235A steel.
中文翻译:
Q235A钢在有色工业含卤离子(F-,Cl-)处理水中的腐蚀行为和电化学性能。
在含有腐蚀性卤素阴离子处理过的水的腐蚀行为和Q235A钢的电化学性能(F - ,氯- )已被研究静态优惠券和动态试样测试,开路电位和线性扫描伏安法的电化学测量的腐蚀试验。结果表明,F的存在-和Cl -的模拟处理后的水离子会加速Q235A钢的腐蚀速率。腐蚀速率达到最大值为F -为50mg / L,CL浓度-浓度分别为200 mg / L。但是,当将施加的电势添加到系统中时,Q235A钢会钝化。同时,启动钝化电位变为正以F - ,氯-浓度的增加。这里是F的影响不大- ,氯-上发起钝化电流密度集中。因此,有必要控制˚F - ,氯-在当通过管道循环处理过的水的浓度由Q235A钢制成。