Interpenetrated Luminescent Metal–Organic Frameworks based on 1H-Indazole-5-carboxylic Acid,Crystal Growth & Design

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Interpenetrated Luminescent Metal–Organic Frameworks based on 1H-Indazole-5-carboxylic Acid
Crystal Growth & Design ( IF 3.2 ) Pub Date : 2020-05-13 , DOI: 10.1021/acs.cgd.0c00345
Antonio A. Garcı́a-Valdivia ₁ , Manuel Pérez-Mendoza ₁ , Duane Choquesillo-Lazarte ₂ , Javier Cepeda ₃ , Belén Fernández ₄ , Manuel Souto _{5,

6} , Marcos González-Tejero ₁ , Jose A. Garcı́a ₇ , Guillermo Mı́nguez Espallargas ₅ , Antonio Rodrı́guez-Diéguez ₁

Affiliation

Herein we report the formation and characterization of two novel Zn-based multifunctional metal–organic frameworks (MOFs) based on 1H-indazole-5-carboxylic acid and bipyridine-like linkers, synthesized by soft solvothermal routes. These materials possess isoreticular 2-fold interpenetrated three-dimensional structures that afford a flexible character and allow porosity modulation of the MOFs as confirmed by CO₂ sorption measurements. Apart from this attractive structural feature, the MOFs exhibit fascinating luminescent properties involving both luminescence thermometry and long-lasting phosphorescence.

中文翻译：

基于1 H-吲唑-5-羧酸的互穿发光金属有机骨架

本文中，我们报道了通过软溶剂热途径合成的基于1 H-吲唑-5-羧酸和联吡啶样连接基的两种新型锌基多功能金属有机骨架（MOF）的形成和表征。这些材料具有其得到挠性字，并允许的MOF的孔隙率调制由CO证实isoreticular 2倍互穿的三维结构₂吸附测量。除了这种引人注目的结构特征外，MOF还具有引人入胜的发光特性，包括发光测温和持久的磷光。

更新日期：2020-07-01

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